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Nanoscale synthesis and optical features of metallic nickel nanoparticles by wet chemical approaches

Identifieur interne : 002944 ( Main/Repository ); précédent : 002943; suivant : 002945

Nanoscale synthesis and optical features of metallic nickel nanoparticles by wet chemical approaches

Auteurs : RBID : Pascal:11-0264799

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English descriptors

Abstract

Nickel nanoparticles (Ni-NPs) were successfully synthesized and attached on indium tin oxide (ITO) substrate by two different methods: from solution reduction process by using sodium borohydride (NaBH4) as reducing agent in the presence of poly(N-vinilpyrrolidone) (PVP) as protective and stabilizing agents and by polyol process under ethylene glycol EG as a solvent. The results indicated that the samples prepared in aqueous solution show the occurrence of face-centered cubic metallic nickel nanoparticles with a medium diameter of ∼31 nm and good size dispersion compared to the preparation in EG that revealed large size ∼150 nm. The dynamics of the nanoparticle's growth in the solvents and comparison with optical absorption is presented.

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<term>Absorption spectra</term>
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<term>Cubic lattices</term>
<term>Dispersions</term>
<term>Ethylene glycol</term>
<term>Indium oxide</term>
<term>Nanomaterial synthesis</term>
<term>Nanometer scale</term>
<term>Nanoparticles</term>
<term>Nanostructured materials</term>
<term>Nanostructures</term>
<term>Nickel</term>
<term>Optical absorption</term>
<term>Sodium</term>
<term>Surface treatments</term>
<term>Tin oxide</term>
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<term>Echelle nanométrique</term>
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<div type="abstract" xml:lang="en">Nickel nanoparticles (Ni-NPs) were successfully synthesized and attached on indium tin oxide (ITO) substrate by two different methods: from solution reduction process by using sodium borohydride (NaBH
<sub>4</sub>
) as reducing agent in the presence of poly(N-vinilpyrrolidone) (PVP) as protective and stabilizing agents and by polyol process under ethylene glycol EG as a solvent. The results indicated that the samples prepared in aqueous solution show the occurrence of face-centered cubic metallic nickel nanoparticles with a medium diameter of ∼31 nm and good size dispersion compared to the preparation in EG that revealed large size ∼150 nm. The dynamics of the nanoparticle's growth in the solvents and comparison with optical absorption is presented.</div>
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